Effect of deposition time on the optical characteristics of. Energy dispersive analysis of xray edax, xray diffraction xrd, selected area electron diffraction patterns saed, uvvisnir spectrophotometer, scanning electron microscopy sem, atomic force microscopy afm, photoluminescence pl and raman spectroscopy. In situ monitoring the role of citrate in chemical bath. Characterisation of chemical bath deposition pbs nanofilms. Xray diffraction analysis shows that the thin films have cubic rock salt type structure with good crystallinity. The glass substrates were first cleaned by liquid detergent and washed thoroughly in distilled water and then it was immersed in boiling water for a few minutes. Chemical bath deposition and characterization of pbs cu.
Materials chemistry and physics 97 2006 7180 structural and optical properties of pbs thin. Lead sulfide pbs thin films were prepared by chemical bath deposition cbd as function of deposition time, ph and deposition rate and the. Synthesis of pbs nanostructures by chemical bath deposition method. The morphological changes of the layers were analyzed using sem and the xrays spectra showing growth on the zinc blende zb face. Nanocrystalline pbs thin films were prepared by chemical bath deposition cbd at 40 2c onto glass substrates and their structural and optical properties. A er completion of the deposition time, samples were removed. Nov 27, 2019 codoped pbs thin films with different co concentrations were synthesized by costeffective chemical bath deposition technique. This film was deposited after 1 hour from chemical bath containing reducing agent and bi ions as doping clement.
Pdf synthesis and characterization of pbs nanowires doped. Chemical bath deposition encompasses a variety of routes for producing functional oxide films and coatings at relatively low temperature by immersing. To obtain film with uniform thickness and low roughness, the glass substrate is tilted at 60 during deposition. Characterization and photoelectrochemical properties of. Effect of deposition parameters on kinematics growth and optical properties of pbs nano films deposited by chemical bath deposition. Beyond min, the solution turned dark gray, indicating the formation of pbs nucleus. In 1933 bruckman deposited leadii sulfide pbs thin film by chemical bath deposition, or solution growth method. By investigating the influence of deposition parameters on the kinematics of the deposited films, we obtained that the deposition rate was dominated by four factors. Optimization of chemical bath deposited cadmium sulfide thin films isaiah 0.
The grain size determined by using xrays spectra for undoped samples. Pbs thin films were successfully prepared by chemical bath deposition at low temperature of 40, 50 and 60c using an improved transparent precursor solution which contained 0. Optical properties of chemical bath deposited lead selenide. Zetoun1 1department of physics, atomic energy commission of syria, p. Pbs is a ivvi semiconductor with a direct bandgap of 0. Chemical bath deposition encompasses a variety of routes for producing functional oxide films and coatings at relatively low temperature by immersing a substrate in a liquid solution. Control of morphology and optical properties of pbs. Pdf synthesis and characterization of pbs nanowires. International journal of electrochemical science, 9, pp.
Lead sulphide pbs thin film was deposit by chemical bath deposition cbd process on the glass substrate at room temperature for various time intervals. The deposition mechanism involves both clusterbycluster and ionbyion growth. For rstminofreactiontime,the solution remained transparent, indicating the occurrence of decomposition reaction. Chemical bath deposition of lead sulphide pbs thin film and. Pbs and pbs cuxs thin films have been deposited on glass substrates using the chemical bath deposition cbd technique.
Cds thin films are a promising electron transport layer in pbs colloidal quantum dot cqd photovoltaic devices. The microstructure and morphology evolution of the. Effect of deposition parameters on kinematics growth and. Photoluminescence study of pbs and pbcds nanocrystalline. It produces good deposits on suitable substrates by the controlled precipitation of the compounds from the. Cus composite thin films grown by cbd method shows that the prepared films have a high transparency ranging from 60 to 80% for photons having wavelength.
Xray line profile analysis of chemically deposited. It is widely used for the deposition of various metal chalcogenide thin films. Effect of deposition time on the optical characteristics. Pbs film has been produced by chemical bath deposition cbd method onto glass substrates using aqueous solution containing pbno 3 2, na 2 so 3, naoh and scnh 2 2. Chemical bath deposition of lead sulphide pbs thin film.
Thin film deposition of pbs is conveniently carried out by chemical reactions of lead acetate with thiourea at room temperature. Lead selenide, chemical bath deposition and optical properties. Synthesis of pbs nanostructures by chemical bath deposition. Characterization of pbs film produced by chemical bath. This paper is dedicated to study the thin polycrystalline films of semiconductor chalcogenide materials cds, cdse, and pbs obtained by ammoniafree chemical bath deposition. Chemical bath deposition of thin pbs nanocrystalline films has been investigated thoroughly for numerous substrates e. Pdf effect of chemical bath deposition parameters on the. Synthesis and electrical, optical, electrochemical. It can be employed for largearea batch processing or continuous deposition. Pdf characterization of pbs nanoparticles synthesized by.
This work presents the structural characterisation of pbs nanofilms deposited by the chemical bath deposition technique at 702 c using polyethyleneimine, triethanolamine and ammonium nitrate as complexing agents, which allow a controlled and constant ion by ion reaction in aqueous medium whose chemical bath reactions take place in basic solutions with typical ph values 912. The obtained films show the formation of well crystallized pbs with a cubic rock. Characterization and simulation of pbs photoconductors. Optical and electrical properties of pbs thin films grown by chemically bath deposition cbd at different lead concentrations mosiori, cliff orori, njoroge, walter n. Optical and electrical properties of pbs thin films grown by. The pbs was deposited from alkaline solution of lead nitrate, thioacetamide, ammonia and triethanolamine that was used as the complexing agent. Pdf lead sulfide pbs thin films were prepared by chemical bath deposition cbd as function of deposition time, ph and deposition rate and the. The films were deposited by ion by ion mechanism on glass substrate, which were finally characterized for structural and optical. The presence of pboh 2 in the asprepared bath is very vital for the deposition of pbs thin films. Synthesis and electrical, optical, electrochemical properties. Photoelectrical characterization indicates that detectors performances depend strongly on oxidant and. The present work deals with the characterization and simulation of lead sulfide pbs photoconductors infrared detectors growth by chemical bath deposition cbd method. Sep 23, 2015 effect of bandaligned double absorber layers on photovoltaic characteristics of chemical bath deposited pbs cds thin film solar cells. It has been attracting wide interest because of its scope of applications in optoelectronics25.
Growth and characterization of cds thin films by chemical. Preparation and characterization of nanocrystalline pbs thin films. Abstract nanocrystalline pbs films were synthesized on ptype si100 wafers using chemical bath deposition. The asgrown pbs was used as substrate to deposit cuxs thin films from alkaline solution of copper nitrate, thiourea, ammonia and. All of the pbs films are polycrystalline in nature with facecentered cubic fcc rock salt structure. Growth and characterization of stoichiometric pbs thin films.
Lead sulfide pbs nanocrystallites have been successfully synthesized using chemical bath deposition cbd method. Pdf a polycrystalline pbs thin films of a thicknesses 0. The xray diffraction procedures showed evidence of polycrystalline films of cubic pbs with a preferred normal orientation of. The average crystallite size varied from 20 to 74 nm, thereby indicating nanocrystalline films with different molar ratios.
Oladeji and lee chow department of physics, university of central florida, orlando, florida 32816, usa abstract we report the optimization of cds thin film grown by chemical bath deposition where homogenous reactions are minimized. Effect of bandaligned double absorber layers on photovoltaic. Chemical bath deposition cbd 1519 is one of the solution phase methods useful for the preparation of compound semiconductors from aqueous solutions. Oladeji and lee chow department of physics, university of central florida, orlando, florida 32816, usa abstract we report the optimization of cds thin film grown by chemical bath. Effects of inhibitor on pbs thin films obtained by chemical bath. Lead sulphide pbs thin films were deposited on glass slide substrates using the chemical bath. Electrochemical studies of pvpcapped pbs thin film deposited. The obtained material is of polycrystalline nature with crystallite of a size that, from a general point of view, should not result in any noticeable quantum confinement.
Lead sulphide pbs nanocrystalline thin films were deposited on silica glass substrate by chemical bath deposition method at a bath temperature of 70 c from six different complexing agents. Thin films of polycrystalline lead sulfide pbs have been deposited on glass substrates by chemical bath deposition at 20 1 c in alkaline. The pbs and cddoped pbs thin films in pva matrix were deposited by chemical bath deposition technique on glass substrate. Characterization of pbs nanoparticles synthesized by chemical. These films can be obtained by several methods such as electrodeposition 20, spray pyrolysis 21, photoaccelerated chemical deposition 10, microwave heating 22 and chemical bath deposition cbd 2324. Atomic force microscopy analysis optical properties dielectric films sulfides thin films xray spectroscopy. Effects of deposition time on the morphology, structure, and optical properties of pbs thin films prepared by chemical bath deposition. High performance pbs colloidal quantum dot solar cells by. The films were characterized using x ray diffraction xrd and scanning electron microscopy sem to understand the pbs structure, morphology and finally correlate cbd process parameters with device performance. Effects of deposition time on the morphology, structure, and. In this study, we have focused on the role of citrate in chemically deposited pbs thin films. Chemical bath deposition cbd, or chemical solution deposition csd, is a method to deposit thin films and nanomaterials, first described in 1869. Trisodium citrate citrate has been commonly used as a cocomplexing agent during chemical bath deposition to improve film quality and control grain size, yet its precise role has not been elucidated to date. Characterization of pbs nanoparticles synthesized by chemical bath deposition.
Growth and characterization of cds thin films by chemical bath deposition dilip maske departmentof physics, d. Pbs thin films are good materials for antireflection coatings and for solar thermal applications in flatplat collectors, house heating for solar chick brooding, etc. Three different solutions bath are used in order to explore the doping effect and oxidant agent on detection capabilities. Effect of deposition time on the optoelectronics properties. Optimization of chemical bath deposited cadmium sulfide.
Optical and electrical properties of pbs thin films grown. Ubale et al structural, optical and electrical properties of nanostructured cds. High resolution tof sims spectra centered at a mz 302 and b mz 447 after pbs chemical bath deposition for 85 mins at 45 c and ph 11 on cooh terminated sams. Lead sulfide pbs powders were prepared by chemical bath deposition cbd method by varying the synthesis temperatures. Optical properties of chemical bath deposited lead. Chemical bath deposition of codoped pbs thin films for solar. We have investigated the chemical bath deposition cbd of pbs on functionalized alkanethiolate selfassembled monolayers sams using timeofflight secondary ion mass spectrometry sims, xray photoelectron spectroscopy xps, and scanning electron microscopy. Effects of relatively high temperature on thin films of. Effects of deposition time on the morphology, structure, and optical properties of pbs thin films prepared by chemical bath deposition b. A comparative study between standard and nanocrystalline pbs thin films was performed. Oct 16, 2017 cds thin films are a promising electron transport layer in pbs colloidal quantum dot cqd photovoltaic devices. Photoluminescence study of pbs and pbcds nanocrystalline thin. Pbs film has been produced by chemical bath deposition cbd method onto.
Pdf synthesis of pbs nanostructures by chemical bath. Figure 1 shows a schematic diagram and possible growth mechanism of the pvpcapped pbs thin. Chemical synthesis of pbs thin films and its physicochemical. The influence of the synthesis temperature and the different molar. Still, there has not been comparative study of the size and density distribution of pbs nanocrystals deposited on different substrates. Morphological control of pbs grown on functionalized self. Some traditional deposition techniques, such as chemical bath deposition and rf radio frequency magnetron sputtering, have been employed to fabricate cds films and cds pbs cqd heterojunction photovoltaic devices. Optical properties of chemical bath deposited lead selenide thin films ezenwa i. Chemical bath deposition, dislocation density, dislocation contrast factor, mwh plot, wh plot i. Pbs thin films by the chemical bath deposition method and understand the growth mechanism and its impact in device tft performance. Chemical bath deposition of codoped pbs thin films for. Nanocrystalline pbs thin films were prepared by chemical bath deposition cbd at 40 2c onto glass substrates and their structural and optical properties modified by insitu doping with hg.
Here we report the preparation and characterization of pbs thin films by chemical bath deposition technique. Atomic force microscopy analysis optical properties dielectric films sulfides thin films x. We denoted standard the pbs film with a good photosensitivity for to use as ir detector. Pbs nanocrystalline thin films were prepared by chemical bath deposition cbd technique. Structural and optical properties of pbs thin films deposited by. Polycrystalline thin films of pbs grown on glass substrates previously coated with pbs colloidal particles in a polyvinyl alcohol solution were obtained by chemical bath deposition cbd. Effects of deposition time on the morphology, structure.
Chemical bath deposition and characterization of pbs cu s. The deposition was carried out at room temperature of 26c and a stirring speed of 60 rpm for an hour. Effect of bandaligned double absorber layers on photovoltaic characteristics of chemical bath deposited pbscds thin film solar cells. Pbs layers by the chemical bath deposition cbd method. The main purpose of this study is to determine thin film which has the best photovoltaic efficiency by examining the photovoltaic properties of codoped pbs with different co concentrations. Nanocrystalline pbs thin films were deposited on glass substrates with various deposition times using chemical bath deposition technique. Characterization of pbs nanoparticles synthesized by. Codoped pbs thin films with different co concentrations were synthesized by costeffective chemical bath deposition technique. For the present studies, the nanocrystalline pbs film and pbs powder are synthesized by chemical bath deposition cbd method which is most convenient and frequently used deposition method to grow thin films on glass substrate. Influence of a polymeric solution buffer layer on the. Pdf preparation of nanocrystalline pbs thin films by chemical.